Publications

Original Articles

1. Functionalized Cyclic Olefin Copolymers: Chemoselective Polymerization of Cyclopropane-Containing Norbornadiene Dimer using Titanium Catalyst and Post-Polymerization Modification
   Yusuke Iwata, Takeshi Shiono, Shin-ichi Matsuoka*
   ChemRxiv
   DOI：10.26434/chemrxiv-2024-6vqqc
2. Highly Tolerant Living/Controlled Anionic Polymerization of Dialkyl Acrylamides Enabled by Zinc Triflate/Phosphine Lewis Pair
   Riki Akita, Shin-ichi Matsuoka*
   ACS Macro Lett. 2024, 13, 1272–1278
   DOI：10.1021/acsmacrolett.4c00514
   ChemRxiv
   DOI：10.26434/chemrxiv-2024-86jl2
3. Hexacyclotetradecenes as Polycyclic Fused exo-Norbornene Monomers: Synthesis of Cyclic Olefin Copolymers via Ti-Catalyzed Efficient Polymerization
   Eri Funahashi, Yusuke Iwata, Shin-ichi Matsuoka*
   Polym. Chem. 2024, 15, 3003-3009
   DOI：10.1039/D4PY00541D
   ChemRxiv
   DOI：10.26434/chemrxiv-2024-bdl9p-v2
4. Anionic or Radical Polymerization Catalyzed by Metal Triflate-Based Lewis Pairs: A Comprehensive Mechanistic Study
   Riki Akita, Mayo Horibe, Katsuhiro Yamamoto, Shin-ichi Matsuoka*
   Macromolecules 2024, 57, 4926–4936
   DOI：10.1021/acs.macromol.4c00830
5. Ring-opening polymerization of six-membered cyclic hybrid dimers composed of an oxoester and thioester
   Mao Hirata, Tomoki Yoshimatsu, Shin-ichi Matsuoka, Susumu Kawauchi, Masato Suzuki*
   Polym. J. 2024, xx, xx-xx
   DOI：10.1038/s41428-024-00915-8
6. Fluorine-driven amorphous solid-state polycondensation: Phosgene-free synthesis of high-molecular weight polycarbonate from fluorinated carbonate
   Taihei Taniguchi, Naoko Shirota, Takashi Okazoe,* Shin-ichi Matsuoka, Katsuhiro Yamamoto and Masato Suzuki*
   Polym. Chem. 2024, 15, 508-515
   DOI：10.1039/D3PY01296D
7. B(C₆F₅)₃-based Lewis pair-catalyzed acrylate polymerization: Lewis base effects on pairing interactions
   Yuka Naganawa, Kazumasa Mori, Shin-ichi Matsuoka,* Masato Suzuki
   Polym. J. 2024, 56, 145-151
   DOI：10.1038/s41428-023-00868-4
8. Spiro-Fluorene-Containing Cyclic Olefin Polymers
   Saki Ishii, Yoshiya Ota, Shin-ichi Matsuoka,* and Masato Suzuki
   ACS Appl. Polym. Mater. 2023, 5, 7614–7620
   DOI：10.1021/acsapm.3c01543
9. Ring-opening metathesis polymerization of ester-functionalized endo-tricyclo[4.2.2.0^2,5]deca-3,9-dienes and thermal properties of the resulting polymers
   Yuta Asano, Hiromi Aoi, Hajime Ohtani, Shin-ichi Matsuoka,* Masato Suzuki
   Polym. Chem. 2023, 14, 1736–1742
   DOI：10.1039/D3PY00052D
10. Synthesis and properties of cyclic olefin polymers by ring-opening metathesis (co)polymerization of α-methyl-substituted norbornene lactones
    Sae Kiyohara, Narumi Miyasako, Yoshiya Ota, Shin-ichi Matsuoka,* Masato Suzuki
    Polym. Chem. 2022, 13, 5882–5888
    DOI：10.1039/D2PY01020H
11. Four Stereoisomeric Norbornadiene Dimers Containing a Cyclopropane Ring: ROMP, Polymer Properties, and Post-Polymerization Modification
    Kazuki Hase, Shin-ichi Matsuoka,* Masato Suzuki
    Macromolecules 2022, 55, 6811–6819
    DOI：10.1021/acs.macromol.2c00902
12. Lewis Pair RAFT Polymerization of Methacrylates on-Water: Evidence of Radical Propagation Mechanism
    Tomoko Koyama, Atsushi Shimizu, Shin-ichi Matsuoka,* Masato Suzuki
    Chem. Lett. 2022, 51, 477–480
    DOI：10.1246/cl.220025
13. Addition Copolymerization of Norbornene Lactone Catalyzed by Pd Complexes
    Kosuke Isaji, Shin-ichi Matsuoka,* Masato Suzuki
    J. Polym. Sci. 2021, 59, 1952–1957
    DOI：10.1002/pol.20210310
14. Cooligomerization of γ-Butyrolactone with (Meth)acrylates Catalyzed by N-Heterocyclic Carbene: Low Possibility of Hybrid Copolymerization
    Takuhiro Nomura, Makoto Ryukan, Shin-ichi Matsuoka,* Masato Suzuki
    Polymer, 2021, 228, 123953
    DOI：10.1016/j.polymer.2021.123953
15. Ring-opening polymerization of thiolactide by using thiol-amine combination
    Masato Suzuki*, Aya Watanabe, Raimu Kawai, Ryo Sato, Shin-ichi Matsuoka, Susumu Kawauchi
    Polymer, 2021, 215, 123386 
    DOI：10.1016/j.polymer.2021.123386
16. Lewis Pair Radical Polymerization “On-Water”
    Kazumasa Mori, Atsushi Shimizu, Mayo Horibe, Momoko Takei, Naoki Awano, Shin-ichi Matsuoka, * and Masato Suzuki
    Macromolecules, 2021, 54, 3–10 
    DOI：10.1021/acs.macromol.0c01969
17. Ring-Opening Metathesis Polymerization of endo- and exo-Norbornene Lactones
    Narumi Miyasako, Shin-ichi Matsuoka,* Masato Suzuki
    Macromol. Rapid Commun. 2021, 42, 200326
    DOI：10.1002/marc.202000326
18. Anionic polymerization of acrylic thioester by using organic base
    Masato Suzuki,* Takumi Kaneko, Yuna Ishikawa, Shin-ichi Matsuoka
    Polym. Chem., 2020, 11, 1145–1150
    DOI：10.1039/C9PY01621J
19. xEnhanced Activity of the Tail-to-tail Dimerization of Michael Acceptors Catalyzed by N-Heterocyclic Carbene and Subsequent Polymer Synthesis from the Resulting Dimers
    Hiroki Kawai, Aoi Fukumoto, Shin-ichi Matsuoka,* and Masato Suzuki
    Chem. Lett. 2019, 48, 558–561
    DOI：10.1246/cl.190097
20. Polycondensation of methacrylates: Auto-tandem organocatalysis using N-heterocyclic carbene
    Aoi Fukumoto, Miharu Arimoto, Shin-ichi Matsuoka,* Masato Suzuki
    Polym. Chem. 2018, 9, 5295–5302
    DOI：10.1039/C8PY01027G
21. Hydrogen-transfer and condensation-addition polymerizations of acrylic acid
    Takuya Murase, Shin-ichi Matsuoka,* Masato Suzuki
    Polym. Chem. 2018, 9, 2984–2990
    DOI：10.1039/C8PY00271A
22. Solid-State Esterification via Ionic-to-Covalent Bond Transformation in Ionic Molecular Crystals Consisting of Disubstituted Anthracene Anion-Cation Combinations
    Masato Suzuki,* Takahiro Fujii, Yoko Naito, Kazuhisa Yamoto, Shin-ichi Matsuoka, Koji Takagi, Haruki Sugiyama, Hidehiro Uekusa
    Bull. Chem. Soc. Jpn. 2018, 91, 343–348
    DOI：10.1246/bcsj.20170349
23. N-Heterocyclic Carbene Initiated Anionic Polymerization of (E,E)-Methyl Sorbate and Subsequent Ring-Closing to Cyclic Poly(alkyl sorbate)
    Yuhei Hosoi, Akinori Takasu,* Shin-ichi Matsuoka, and Mikihiro Hayashi
    Am. Chem. Soc. 2017, 139, 15005–15012
    DOI：10.1021/jacs.7b06897
24. Oxa-Michael Addition Reaction and Polymerization of Morita–Baylis–Hillman Adducts and Derivatives 
    Shin-ichi Matsuoka,* Yuki Hoshiyama, Kanae Tsuchimoto, Masato Suzuki
    Chem. Lett. 2017, 46, 1718–1720
    DOI：10.1246/cl.170794
25. Ring-Opening Polymerization of Donor-Acceptor Cyclopropanes Catalyzed by Lewis Acids
    Kosuke Hayakawa, Shin-ichi Matsuoka,* Masato Suzuki
    Polym. Chem. 2017, 8, 3841–3847
    DOI：10.1039/C7PY00794A
26. Tail-to-Tail Cross-Dimerization of Methyl Methacrylate/Methacrylonitrile with Acrylates Catalyzed by N-Heterocyclic Carbene
    Shin-ichi Matsuoka,* Yuki Fukumoto, Masato Suzuki
    Chem. Lett. 2017, 46, 983–986
    DOI：10.1246/cl.170263
27. Post-polymerization modification of unsaturated polyesters by Michael addition of N-heterocyclic carbenes
    Shin-ichi Matsuoka,* Yuya Kamijo, Masato Suzuki
    Polym. J. 2017, 49, 423–428
    DOI：10.1038/pj.2017.2
28. Tail-to-Tail Dimerization and Rauhut-Currier Reaction of Disubstituted Michael Acceptors Catalyzed by N-Heterocyclic Carbene
    Shin-ichi Matsuoka,* Naoki Awano, Masanori Nakazawa, Masato Suzuki
    Tetrahedron Lett. 2016, 57, 5707–5711
    DOI：10.1016/j.tetlet.2016.11.031
29. N-Heterocyclic carbene-mediated redox condensation of alcohols
    Terumasa Kato, Shin-ichi Matsuoka,* Masato Suzuki
    Chem. Commun. 2016, 52, 8569–8572
    DOI：10.1039/C6CC04154J
30. Thiol-Mediated Controlled Ring-Opening Polymerization of Cysteine-Derived β-Thiolactone and Unique Features of Product Polythioester
    Masato Suzuki,* Kazumasa Makimura, Shin-ichi Matsuoka
    Biomacromolecules 2016, 17 1135–1141
    DOI：10.1021/acs.biomac.5b01748
31. Lewis Acid-Catalyzed Ring-Opening Addition Reactions of Alcohols to Vinylcyclopropane
    Shin-ichi Matsuoka,* Kazuki Numata, Masato Suzuki
    Chem. Lett. 2015, 44, 1532–1534
    DOI：10.1246/cl.150737
32. Transfer hydrogenation promoted by N-heterocyclic carbene and water
    Terumasa Kato, Shin-ichi Matsuoka,* Masato Suzuki
    Chem. Commun. 2015, 51, 13906–13909
    DOI：10.1039/C5CC05117G
33. Expanding the Scope of the Tail-to-Tail Dimerization of Vinyl Compounds Catalyzed by N-Heterocyclic Carbene
    Shin-ichi Matsuoka,* Masanori Nakazawa, Masato Suzuki
    Bull. Chem. Soc. Jpn. 2015, 88, 1093–1099
    DOI：10.1246/bcsj.20150048
34. Diastereoselective Cyclization of Aminobenzoic Acid Derivative and Chiroptical Properties of Triple-Stranded Helical Bis(phenylethynyl)benzene
    Ryohei Yamakado, Shin-ichi Matsuoka, Masato Suzuki, Daisuke Takeuchi, Hyuma Masu, Isao Azumaya, and Koji Takagi*
    Chem. Commun. 2015, 51, 5710–5713
    DOI：10.1039/c5cc00945f
35. Solid-State Polycondensation via Ionic-to-Covalent Bond Transformation to Control Polymer Structure: Preparation of Porphyrin-Based Ladder Polymer
    Masato Suzuki,* Kohei Yokota, Hiroe Tsuchida, Kazuhisa Yamoto, Masayuki Nagata, Shin-ichi Matsuoka, Koji Takagi, Kohei Johmoto, and Hidehiro Uekusa
    ACS Macro Lett. 2015, 4, 247–250
    DOI：10.1021/acsmacrolett.5b00013
36. Oxa-Michael Addition Polymerization of Acrylates Catalyzed by N-Heterocyclic Carbenes
    Shin-ichi Matsuoka,* Shoko Namera, Masato Suzuki
    Polym. Chem. 2015, 6, 294–301
    DOI：10.1039/C4PY01184H
37. Cooperative N-Heterocyclic Carbene/Brønsted Acid Catalysis for the Tail-to-Tail (Co)dimerization of Methacrylonitrile
    Terumasa Kato, Shin-ichi Matsuoka,* Masato Suzuki
    Org. Chem. 2014, 79, 4484–4491
    DOI：10.1021/jo500514e
38. Synthesis, reaction, and optical properties of cyclic oligomers bearing 9,10-diphenylanthracene based on an aromatic tertiary amide unit
    Ryohei Yamakado, Shin-ichi Matsuoka, Masato Suzuki, Daisuke Takeuchi, Hyuma Masu, Isao Azumaya and Koji Takagi*
    RSC Adv., 2014, 4, 6752–6760
    DOI：10.1039/c3ra46652c
39. N-Heterocyclic Carbene-Catalyzed Cyclotetramerization of Acrylates
    Shin-ichi Matsuoka,* Shoko Namera, Atsushi Washio, Koji Takagi, and Masato Suzuki
    Org. Lett. 2013, 15, 5916–5919
    DOI：10.1021/ol4021942
40. Experimental Mechanistic Studies of the Tail-to-Tail Dimerization of Methyl Methacrylate Catalyzed by N-Heterocyclic Carbene
    Terumasa Kato, Yoshiya Ota, Shin-ichi Matsuoka,* Koji Takagi, and Masato Suzuki
    Org. Chem. 2013, 78, 8739–8747
    DOI：10.1021/jo401477b
41. Helicity Induction in Three π-Conjugated Chromophores by Planar Chirality of Calixamide
    Ryohei Yamakado, Koichiro Mikami,* Koji Takagi,* Isao Azumaya,* Shinri Sugimoto, Shin-ichi Matsuoka, Masato Suzuki, Kosuke Katagiri, Masanobu Uchiyama, and Atsuya Muranaka
    Chem. Eur. J. 2013, 19, 11853–11857
    DOI：10.1002/chem.201301198
42. Synthesis and ring-opening reaction of novel 1,3-dehydroadamantanes possessing phenyl and alkoxyl substituents
    Sotaro Inomata, Yusuke Harada, Shin-ichi Matsuoka, Takashi Ishizone*
    Tetrahedron 2013, 69, 3238–3248
    DOI：10.1016/j.tet.2013.02.042
43. A screw-shaped alignment of pyrene using m-calix[3]amide
    Ryohei Yamakado, Shin-ichi Matsuoka, Masato Suzuki, Koji Takagi*, Kosuke Katagiri, Isao Azumaya
    Tetrahedron 2013, 69, 1516–1520
    DOI：10.1016/j.tet.2012.12.015
44. Sequential one-pot and three-component reactions of an N-heterocyclic carbene to form 4-(1,2,4-triazol-5-ylidene)pyrrolidine-2,5-diones: a tandem umpolung/annulation sequence via deoxy-Breslow intermediates
    Shin-ichi Matsuoka*, Yusuke Tochigi, Koji Takagi, Masato Suzuki
    Tetrahedron 2012, 68, 9836–9841
    DOI：10.1016/j.tet.2012.08.076
45. Ring-Opening Polymerizations of 1,3-Dehydroadamantanes: Synthesis of Novel Thermally Stable Poly(1,3-adamantane)s
    Sotaro Inomata, Shin-ichi Matsuoka, Shiko Sakai, Hiroyuki Tajima, and Takashi Ishizone*
    Macromolecules 2012, 45, 4184–4195
    DOI：10.1021/ma300395s
46. Preparation of Molecular Cage by Coordination of m-Calix[3]amide bearing Pyridine with Palladium Complex
    Ryohei Yamakado, Shinri Sugimoto, Shin-ichi Matsuoka, Masato Suzuki, Yasuhiro Funahashi, and Koji Takagi*
    Chem. Lett., 2012, 41, 249–251
    DOI：10.1246/cl.2012.249
47. Organocatalytic Head-to-Tail Dimerization of Methacrolein via Conjugate Addition of Methanol: An Alcohol Activation Mechanism Proved by Electrospray Ionization Mass Spectrometry
    Shin-ichi Matsuoka*, Shintaro Shimakawa, Koji Takagi, Masato Suzuki
    Tetrahedron Lett. 2011, 52, 6835–6838
    DOI：10.1016/j.tetlet.2011.10.070
48. Organocatalytic Tail-to-Tail Dimerization of Olefin: Umpolung of Methyl Methacrylate Mediated by N-Heterocyclic Carbene
    Shin-ichi Matsuoka*, Yoshiya Ota, Atsushi Washio, Akiho Katada, Kenji Ichioka, Koji Takagi, Masato Suzuki
    Org. Lett. 2011, 13, 3722–3725
    DOI：10.1021/ol201380m
49. Syntheses of Aliphatic Polycarbonates from 2’-Deoxyribonucleosides
    Masato Suzuki,* Toyokazu Sekido, Shin-ichi Matsuoka, and Koji Takagi
    Biomacromolecules 2011, 12, 1449–1459
    DOI：10.1021/bm101328j
50. Poly(ethylene glycol)-Induced Acceleration of Free Radical Polymerization of Methyl Methacrylate: Effects of Highly Viscous Solvent and Kinetic Study
    Shin-ichi Matsuoka,* Takashi Kikuno, Koji Takagi, and Masato Suzuki
    Polym. J. 2010, 42, 368–374
    DOI：10.1038/pj.2010.17
51. Polymerization of Fluorene-Based Monomers Modified with Thiavinylidene Structure at 9-Position and Their Optical Properties
    Koji Takagi,* Shinri Sugimoto, Manabu Mitamura, Shin-ichi Matsuoka, and Masato Suzuki
    Synth. Met. 2009, 159(3-4), 228–233.
    DOI：10.1016/j.synthmet.2008.09.009
52. Tropolone-terminated Oligomeric Fluorophores Having Responsive Properties to External Environment
    Koji Takagi,* Kazuhiro Saiki, Hirokazu Hayashi, Hiroyasu Ohsawa, Shin-ichi Matsuoka, and Masato Suzuki
    Bull. Chem. Soc. Jpn. 2009, 82(2), 236–241.
    DOI：10.1246/bcsj.82.236
53. Conjugated Oligomers Containing Imidazole in Main Chain with Intramolecular Hydrogen Bonding
    Koji Takagi*, Kenta Sugihara, Junya Ohta, Yasuo Yuki, Shin-ichi Matsuoka and Masato Suzuki
    Polymer J. 2008, 40, 614–621
    DOI：10.1295/polymj.PJ2008045
54. Polymeric Oligothiophene Fluorophores Spatially Isolated by Spirobifluorene and Their Emission Properties.
    Koji Takagi*, Masaki Momiyama, Junya Ohta, Yasuo Yuki, Shin-ichi Matsuoka, Masato Suzuki   
    Macromolecules 2007, 40, 8807–8811. 
    DOI：10.1021/ma071410b
55. Spontaneous Copolymerization of 1,3-Dehydroadamantane.
    Takashi Ishizone*, Shin-ichi Matsuoka, Naoto Ogiwara, Yosuke Uehara, Shingo Kobayashi
    Macromol. Symp. 2007, 249-250, 373–377
    DOI： DOI：10.1002/masy.200750406
56. Living Anionic Polymerizations of 4-(1-Adamantyl)styrene and 3-(4-Vinylphenyl)-1,1′-biadamantane.
    Shingo Kobayashi, Takahiro Matsuzawa, Shin-ichi Matsuoka, Hiroyuki Tajima, Takashi Ishizone*
    Macromolecules 2006, 39, 5979–5986
    DOI：10.1021/ma060977+
57. Formation of Alternating Copolymers via Spontaneous Copolymerization of 1,3-Dehydroadamantane with Electron-Deficient Vinyl Monomers.
    Shin-ichi Matsuoka, Naoto Ogiwara, Takashi Ishizone*
    J. Am. Chem. Soc. 2006, 128, 8708–8709
    DOI：10.1021/ja062157i
58. Cationic Ring-Opening Polymerization of 1,3-Dehydroadamantanes.
    Shin-ichi Matsuoka, Naoto Ogiwara, Yosuke Uehara, Takashi Ishizone*
    Macromol. Symp. 2006, 240, 206–212
    DOI： DOI：10.1002/masy.200650825
59. Synthesis of Poly(1,3-adamantane)s by Cationic Ring-Opening Polymerization of 1,3-Dehydroadamantanes.
    Takashi Ishizone*, Shin-ichi Matsuoka, Shiko Sakai, Wataru Harada, Hiroyuki Tajima
    Macromolecules 2004, 37, 7069–7071
    DOI：10.1021/ma048925c
60. Synthesis of Tetramers of 1,3-Adamantane Derivatives.
    Takashi Ishizone*, Hiroyuki Tajima, Shinichi Matsuoka, Seiichi Nakahama
    Tetrahedron Lett. 2001, 42, 8645–8647
    DOI：10.1016/S0040-4039(01)01825-1

Reviews and Books

1. 開環重合の基礎と最近の展開
   鈴木 将人，松岡 真一
   日本接着学会誌, 2022, 58, 361–368
2. 脂肪族ポリエステルの新規合成プロセスの開発
   松岡 真一
   新東技報, 2019, 37, 71–72
3. 新しい高分子材料の開発を目指して～重合触媒やモノマーの化学構造に着目して～ 
   松岡 真一
   中部経済新聞「研究現場発」2019
4. 天然高分子と合成高分子：錦織選手のラケット
   松岡 真一
   高分子未来塾   2016
5. N-Heterocyclic carbene-catalyzed dimerization, cyclotetramerization and polymerization of Michael acceptors
   Shin-ichi Matsuoka*
   Polym. J., 2015, 47, 713–718
   DOI： 10.1038/pj.2015.59
6. Organocatalytic Dimerization of Vinyl Monomers: New Synthetic Route to Condensation Polymers
   Shin-ichi Matsuoka
   高分子, 2014, 63, 710
7. Frustrated Lewis Pairと高分子合成
   松岡 真一
   化学と工業, 2014, 67, 768–769
8. 在外研究MAP University of Toronto
   松岡 真一
   ペトロテック, 2014, 37, 460–461
9. Chain-Growth Copolymerization (Overview)
   Shin-ichi Matsuoka
   Encyclopedia of Polymeric Nanomaterials 2013, 1, 357–360 SpringerReference 
10. 拡大ITPの支援によるトロント大学144日間
    松岡 真一
    ごきそ, 2013, 455, 1–3
11. 有機触媒によるリビング重合
    松岡 真一
    化学と工業, 2011, 64, 236–237
12. 有機触媒は地球温暖化防止に貢献できるか：N-ヘテロ環状カルベン触媒が二酸化炭素を還元する
    松岡 真一
    化学, 2010, 65, 68–69
13. N-ヘテロ環状カルベン化学の新展開：高分子合成への応用
    松岡 真一
    有機合成化学協会誌, 2010, 68, 659–660
14. アクリル酸メチルとオレフィン類とのラジカル共重合
    松岡 真一
    化学と工業, 2005, 58, 1087